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Heliotropin (Piperonal)

Chemical Name: 3,4-Methylenedioxybenzaldehyde

Common Name: Piperonal (also known as Heliotropin in perfumery)

Molecular Formula: C₈H₆O₃

Molecular Weight: 150.13 g/mol

CAS Number: 120-57-0

Appearance: White crystalline solid

Odor: Sweet, powdery, vanilla-like, almondy, floral (heliotrope-like)

Melting Point: 36–39°C

Boiling Point: ~263°C (505°F)

Solubility: Slightly soluble in water; soluble in alcohol and oils

Functional Group: Aromatic aldehyde

Perfumery Profile

Scent Profile:

  • Sweet and floral, with strong resemblance to heliotrope flowers
  • Notes of vanilla, almond, and powder
  • Slightly balsamic and comforting
  • Often described as having a “marzipan” or play-dough warmth

Use in Perfumery:

  • Used to create soft, sweet, comforting notes in floral, gourmand, and powdery fragrances
  • Often included in orientals, amber, floral, and vintage-style perfumes
  • Enhances notes like vanilla, tonka bean, violet, and almond
  • A key player in baby powder and soft cosmetic accords

Fragrance Families:

  • Floral (especially heliotrope and violet-based)
  • Gourmand
  • Powdery
  • Oriental
  • Balsamic

Natural Source:

  • Found in trace amounts in vanilla beans, tonka beans, and black pepper, but almost always synthetically produced for perfumery

Notable Uses:

  • Common in classic compositions such as L’Heure Bleue by Guerlain and Kenzo Flower
  • Frequently used in creating “cosmetic powder” accords and nostalgic scent profiles

Cinnamic Aldehyde